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Some Basic Concepts of Chemistry — Class 11 ISC Chemistry revision notes

A 5-page visual revision sheet for Some Basic Concepts of Chemistry, written for Class 11 ISC Chemistry. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.

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Some Basic Concepts of Chemistry in one look

the mole, and every calculation that hangs off it

Matter, in the words the paper marks

  • a pure substance has a fixed composition throughout: an element cannot be broken into simpler substances chemically, a compound can, and its parts are present in a fixed mass ratio
  • a mixture has no fixed composition; homogeneous means one visible phase (air, brine) and heterogeneous means more than one (sand in water)
  • a physical property can be measured without changing what the substance is (density, melting point, colour); a chemical property only shows up when it becomes something else
  • the SI base quantities used here are mass in kg, amount of substance in mol, temperature in K, and the derived ones that matter are volume, density and concentration

Significant figures, which are marks not decoration

  • every non zero digit counts; zeros between digits count; leading zeros never count; trailing zeros count only when a decimal point is written
  • adding or subtracting, the answer keeps the FEWEST decimal places; multiplying or dividing, it keeps the FEWEST significant figures
  • round the final answer once, at the end, never at each step, and round 5 to the nearest even digit
  • accuracy is closeness to the true value, precision is closeness of repeated readings to each other, and a set can be precise and badly wrong

The factor label method, which turns a conversion into cancelling

  • write the quantity you have, multiply by a fraction equal to 1 whose top carries the unit you want and whose bottom carries the unit you are killing
  • keep multiplying until only the wanted unit survives, and the arithmetic is then just numbers
  • the same trick converts a density into a volume, a molarity into a mass, and grams into moles, so it is worth writing out in full in a long question
  • if the units do not cancel to the answer's unit, the setup is wrong and no amount of arithmetic will rescue it

The laws of chemical combination

  • conservation of mass: matter is neither created nor destroyed in a chemical change, so a balanced equation is a mass statement before it is anything else
  • definite proportions: a given compound always holds the same elements in the same fixed mass ratio, however it was made
  • multiple proportions: when two elements form more than one compound, the masses of one combining with a fixed mass of the other are in a small whole number ratio, as in CO and CO_2 where the oxygen masses go 1 to 2
  • Gay Lussac, gaseous volumes: gases react in volumes that bear a simple whole number ratio, at the same temperature and pressure
  • Avogadro: equal volumes of all gases under the same conditions hold equal numbers of molecules, which is what separated an atom from a molecule at last

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