Organic Chemistry – Some Basic Principles and Techniques — Class 11 CBSE Chemistry revision notes
A 4-page visual revision sheet for Organic Chemistry – Some Basic Principles and Techniques, written for Class 11 CBSE Chemistry. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.
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Organic Chemistry – Some Basic Principles and Techniques in one look
one carbon skeleton, one functional group, and the rules that name and break both
Classifying carbon skeletons
Open chain (acyclic): carbon atoms in a straight or branched chain, no ring anywhere, e.g. butane
Alicyclic: carbon atoms joined into a ring, but not the special benzene-type ring, e.g. cyclohexane
Aromatic: built around benzene's ring, a delocalised, unusually stable pi system, e.g. toluene
IUPAC nomenclature, the four steps
find the longest chain containing the principal characteristic group, if there is one
that chain's carbon count fixes the root word (meth, eth, prop, but, pent…)
number the chain so the principal group gets the lowest locant (or first point of difference)
name every branch as a substituent prefix, alphabetised, each with its own locant
assemble: locants + substituent prefixes + root + suffix for the principal group, e.g. 4-methylpentanoic acid
Suffixes for the common functional groups, by falling seniority
Group
Suffix
Example
-COOH, carboxylic acid
-oic acid
ethanoic acid
-CHO, aldehyde
-al
ethanal
>C=O, ketone
-one
propan-2-one
-OH, alcohol
-ol
ethanol
-NH_2, amine
-amine
ethanamine
C=C, alkene
-ene
ethene
C≡C, alkyne
-yne
ethyne
Structural isomerism, in four flavours
chain isomerism: same molecular formula, the carbon skeleton itself branches differently, e.g. butane and 2-methylpropane
position isomerism: same skeleton and group, at a different carbon, e.g. propan-1-ol/-2-ol
functional isomerism: same formula, genuinely different functional groups
e.g. ethanol (alcohol) and dimethyl ether (ether), both C_2H_6O
metamerism: same functional group, different alkyl groups either side of it
e.g. diethyl ether and methyl propyl ether, both C_4H_10O
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What this Organic Chemistry – Some Basic Principles and Techniques sheet covers
Classifying carbon skeletons
Open chain (acyclic)
Alicyclic
Aromatic
IUPAC nomenclature, the four steps
Suffixes for the common functional groups, by falling seniority
Structural isomerism, in four flavours
Stereoisomerism: same bonds, different arrangement in space
Worked: classifying a reaction by type
Inductive effect: a bond, not a jump
Resonance, hyperconjugation, electromeric effect
Reaction intermediates
Carbocation
Carbanion
Free radical
Carbene
The three basic reaction types, by what happens to the bonds
Purification techniques, matched to what's wrong with the sample
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