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Organic Chemistry – Some Basic Principles and Techniques — Class 11 CBSE Chemistry revision notes

A 4-page visual revision sheet for Organic Chemistry – Some Basic Principles and Techniques, written for Class 11 CBSE Chemistry. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.

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Organic Chemistry – Some Basic Principles and Techniques in one look

one carbon skeleton, one functional group, and the rules that name and break both

Classifying carbon skeletons

  • Open chain (acyclic): carbon atoms in a straight or branched chain, no ring anywhere, e.g. butane
  • Alicyclic: carbon atoms joined into a ring, but not the special benzene-type ring, e.g. cyclohexane
  • Aromatic: built around benzene's ring, a delocalised, unusually stable pi system, e.g. toluene

IUPAC nomenclature, the four steps

  • find the longest chain containing the principal characteristic group, if there is one
  • that chain's carbon count fixes the root word (meth, eth, prop, but, pent…)
  • number the chain so the principal group gets the lowest locant (or first point of difference)
  • name every branch as a substituent prefix, alphabetised, each with its own locant
  • assemble: locants + substituent prefixes + root + suffix for the principal group, e.g. 4-methylpentanoic acid

Suffixes for the common functional groups, by falling seniority

GroupSuffixExample
-COOH, carboxylic acid-oic acidethanoic acid
-CHO, aldehyde-alethanal
>C=O, ketone-onepropan-2-one
-OH, alcohol-olethanol
-NH_2, amine-amineethanamine
C=C, alkene-eneethene
C≡C, alkyne-yneethyne

Structural isomerism, in four flavours

  • chain isomerism: same molecular formula, the carbon skeleton itself branches differently, e.g. butane and 2-methylpropane
  • position isomerism: same skeleton and group, at a different carbon, e.g. propan-1-ol/-2-ol
  • functional isomerism: same formula, genuinely different functional groups
  • e.g. ethanol (alcohol) and dimethyl ether (ether), both C_2H_6O
  • metamerism: same functional group, different alkyl groups either side of it
  • e.g. diethyl ether and methyl propyl ether, both C_4H_10O

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