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Kinetic Theory of Gases and Radiation — Class 12 Maharashtra HSC Physics revision notes

A 6-page visual revision sheet for Kinetic Theory of Gases and Radiation, written for Class 12 Maharashtra HSC Physics. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.

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Kinetic Theory of Gases and Radiation in one look

molecules make pressure, temperature is energy, and hot things glow

The gas laws and the ideal gas equation

  • Boyle, at constant T V ∝ 1/P
  • Charles, at constant P V ∝ T
  • Gay-Lussac, at constant V P ∝ T
  • combined, for a fixed mass P_1V_1/T_1 = P_2V_2/T_2
  • ideal gas equation PV = nRT
  • per molecule PV = Nk_BT,quad R = N_Ak_B

The assumptions behind the model

  • ~10^23 molecules a mole: tracking one is hopeless, so the theory averages over all
  • spread uniformly, moving randomly in straight lines at constant velocity between collisions
  • collisions perfectly elastic, with each other and the walls: kinetic energy conserved
  • force only during a collision; the collision time itself negligible
  • ignoring molecule-molecule collisions for pressure is fair: the mean free path grows as P drops

Ideal gas vs real gas

Ideal
  • obeys PV = nRT at every pressure and temperature
  • no intermolecular interactions at all
  • point molecules, no volume of their own
Real
  • molecules do interact, so no real gas is truly ideal
  • close to ideal at low density: low pressure or high temperature
  • and well above its liquefaction temperature

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