Chemical Bonding — Class 11 Maharashtra HSC Chemistry revision notes
A 7-page visual revision sheet for Chemical Bonding, written for Class 11 Maharashtra HSC Chemistry. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.
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Chemical Bonding in one look
why atoms pair up, and the shape, strength and energy that pairing leaves behind
Kossel-Lewis approach
only outermost-shell electrons decide bond formation
a bond forms by loss/gain of electrons (ionic) or by sharing a pair (covalent)
Lewis pictured the atom as a positive kernel (nucleus + inner electrons) around a valence shell
the valence shell holds at most eight electrons: the octet
octet rule: an atom loses, gains or shares electrons until its shell holds eight
H and Li are content with two, like He (a duplet), the rule breaking down there
not valid generally: it fails incomplete octets, expanded octets and odd-electron species
Ionic bond: NaCl and CaCl2
Na (2,8,1) loses one electron to reach Ne (2,8)
Cl (2,8,7) gains one to reach Ar (2,8,8): Na^+ and Cl^- attract electrostatically
CaCl_2: Ca (2,8,8,2) loses two electrons to two separate Cl atoms
giving Ca^2+ and two Cl^-
ionic bonds form readily between a low-ionisation-enthalpy metal and a large negative electron gain enthalpy element
both processes happen in the gaseous phase before the solid crystallises
Ionic bond vs covalent bond
Ionic
complete transfer of electrons, metal to non-metal
e.g. Na loses an electron, Cl gains it: Na^+Cl^-
held by electrostatic attraction, no fixed direction
conducts electricity molten or in solution
Covalent
electrons shared, usually between two non-metals
single bond shares one pair, double two, triple three
e.g. two Cl atoms share one pair in Cl_2
has a definite direction, which is why molecules have shape
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What this Chemical Bonding sheet covers
Kossel-Lewis approach
Ionic bond: NaCl and CaCl2
Ionic bond vs covalent bond
Ionic
Covalent
Ionic solids and lattice enthalpy
Lattice enthalpy, some values
Covalent bond and Lewis structures
Formal charge
formal charge on an atom in a Lewis structure
CO, structure C≡O: formal charge on C
Limitations of the octet rule
VSEPR: predicting shape from repulsion
VSEPR shapes, by lone pair count
Valence bond theory
Hybridisation
Worked: BeCl2, why hybridise at all
Molecular orbital theory
Bond order from MO theory
bond order
H_2, config σ1s^2: 2 bonding, 0 antibonding
N_2, config through σ2p_z^2: 10 bonding, 4 antibonding
O_2, two electrons singly fill π^*: 10 bonding, 6 antibonding
F_2, config through π^*2p^4: 10 bonding, 8 antibonding
Reading a bond order
O2's paramagnetism
Bond parameters
bond length, H-Cl
bond angle, H-O-H
bond enthalpy of H_2 (dissociation energy, since H_2 is diatomic)
average O-H bond enthalpy in H_2O, from two unequal successive steps
Dipole moment
Fajans' rules: covalent character in an ionic bond
These notes are not a standalone PDF. CapCompass plans Chemistry chapter by chapter against your real exam dates and free hours, and when the plan reaches Chemical Bonding the sheet opens inside the study block itself — at the page covering the sub-topic that block is on, with the timer still running. Revision arrives at the moment the plan says revise, instead of having to be gone looking for.