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Chemical Bonding — Class 11 Maharashtra HSC Chemistry revision notes

A 7-page visual revision sheet for Chemical Bonding, written for Class 11 Maharashtra HSC Chemistry. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.

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Chemical Bonding in one look

why atoms pair up, and the shape, strength and energy that pairing leaves behind

Kossel-Lewis approach

  • only outermost-shell electrons decide bond formation
  • a bond forms by loss/gain of electrons (ionic) or by sharing a pair (covalent)
  • Lewis pictured the atom as a positive kernel (nucleus + inner electrons) around a valence shell
  • the valence shell holds at most eight electrons: the octet
  • octet rule: an atom loses, gains or shares electrons until its shell holds eight
  • H and Li are content with two, like He (a duplet), the rule breaking down there
  • not valid generally: it fails incomplete octets, expanded octets and odd-electron species

Ionic bond: NaCl and CaCl2

  • Na (2,8,1) loses one electron to reach Ne (2,8)
  • Cl (2,8,7) gains one to reach Ar (2,8,8): Na^+ and Cl^- attract electrostatically
  • CaCl_2: Ca (2,8,8,2) loses two electrons to two separate Cl atoms
  • giving Ca^2+ and two Cl^-
  • ionic bonds form readily between a low-ionisation-enthalpy metal and a large negative electron gain enthalpy element
  • both processes happen in the gaseous phase before the solid crystallises

Ionic bond vs covalent bond

Ionic
  • complete transfer of electrons, metal to non-metal
  • e.g. Na loses an electron, Cl gains it: Na^+Cl^-
  • held by electrostatic attraction, no fixed direction
  • conducts electricity molten or in solution
Covalent
  • electrons shared, usually between two non-metals
  • single bond shares one pair, double two, triple three
  • e.g. two Cl atoms share one pair in Cl_2
  • has a definite direction, which is why molecules have shape

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