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Nuclear Chemistry and Radioactivity — Class 11 Maharashtra HSC Chemistry revision notes

A 6-page visual revision sheet for Nuclear Chemistry and Radioactivity, written for Class 11 Maharashtra HSC Chemistry. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.

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Nuclear Chemistry and Radioactivity in one look

what holds a nucleus together, what makes some fall apart, and how fast they do it

Inside the Nucleus

  • a nucleus is written ^A_ZX: Z is proton count, A is protons+neutrons, N=A-Z
  • the nucleus is tiny: radius ~10^-15 m vs the atom's ~10^-10 m, a factor of 10^5
  • picture the atom as a football stadium: the nucleus is a pea at the centre spot
  • nuclear radius: R=R_0A^1/3 (R_0=1.33Ɨ10^-15 m), so nuclear VOLUME is proportional to A
  • an electron weighs only 1/1837 of a proton, so the nucleus holds nearly the whole atomic mass
  • packed into that tiny volume, nuclear density runs ~10^15 times ordinary matter

Classifying Nuclides by Composition

  • isotopes: SAME Z, different N (and A), e.g. ^22_11Na, ^23_11Na, ^24_11Na
  • isobars: SAME A, different Z and N, e.g. ^14_6C and ^14_7N
  • isotones: SAME N, different Z and A, e.g. ^13_6C and ^14_7N, both N=7
  • mirror nuclei: isobars whose p and n counts differ by exactly 1, simply swapped
  • e.g. ^3_1H (N=2) and ^3_2He (N=1)
  • nuclear isomers: same Z AND N (same A), differing only in ENERGY state
  • the higher-energy one is metastable, marked 'm', e.g. ^60mCo next to ^60Co

Even-Odd Rule and the N/Z Stability Belt

  • of stable nuclides, 165 have even Z and even N (~85% of the earth's crust)
  • only 4 have odd Z AND odd N (~2%): even-even pairing is the most stable arrangement
  • protons pair with protons, neutrons with neutrons (no p-n pairing bonus)
  • so odd-Z/even-N and even-Z/odd-N counts (55, 50) come out nearly equal
  • plotting N against Z for every stable nuclide traces a narrow STABILITY BELT
  • nuclides falling outside that belt are radioactive
  • for light nuclei (below ^40_20Ca) the belt tracks N=Z, N/Zā‰ˆ1
  • for heavier nuclei it curves upward: more neutrons space out the repelling protons

Magic Numbers and Nuclear Potential

  • nuclei with 2, 8, 20, 28, 50, 82, 126 p or n are 'magic', unusually stable
  • e.g. ^208_82Pb is doubly magic: 82 protons AND 126 neutrons
  • protons sit ~10^-15 m apart: coulombic repulsion alone would blow the nucleus apart
  • a short-range NUCLEAR force between every nucleon pair (charge-independent) overpowers that repulsion
  • this net attraction is the nuclear potential, which binding energy measures the strength of

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