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Structure of Atom — Class 11 Maharashtra HSC Chemistry revision notes

A 5-page visual revision sheet for Structure of Atom, written for Class 11 Maharashtra HSC Chemistry. Formulas, diagrams and the traps that cost marks, laid out to be read the night before rather than the term before. Free, and it opens inside CapCompass.

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Structure of Atom in one look

one nucleus, a set of shells, and rules for who lives where

Three subatomic particles

  • Electron: e^-, J.J. Thomson, 1897, cathode-ray tube. charge -1, mass ≈1/1837 of a proton's
  • Proton: Rutherford, 1911-1919, alpha scattering and nitrogen transmutation. charge +1, mass ≈1 u
  • Neutron: Chadwick, 1932, paraffin bombarded by beryllium radiation. no charge, mass ≈1 u, a shade above a proton's

Rutherford's alpha-scattering experiment

  • a beam of α particles fired at a thin gold foil, only a few atoms thick
  • most passed straight through undeflected: the atom is mostly empty space
  • a small fraction deflected through large angles, about 1 in 20,000 bounced almost straight back
  • that rebound meant a tiny, dense, positively charged core: the nucleus
  • 1919: fast α particles turned nitrogen into oxygen, always releasing hydrogen, later renamed the proton

Rutherford's nuclear model, and where it broke

  • mass and positive charge sit in a tiny nucleus (~10^-15 m), electrons revolve outside (~10^-10 m)
  • modelled electrons like planets orbiting the nucleus under electrostatic attraction
  • problem 1: an orbiting charge must radiate energy, so it should spiral in instantly, yet atoms don't
  • problem 2: says nothing about why an electron sits at a given distance or hydrogen's line spectrum

Atomic number, mass number, notation

  • atomic number, fixes the element Z=p=e (in a neutral atom)
  • mass number, protons + neutrons A=Z+N
  • standard notation for a nuclide ^A_ZX

Isotopes, isobars and isotones

  • isotopes: same Z, different A, identical chemical behaviour, e.g. ^35_17Cl and ^37_17Cl
  • isobars: same A, different Z, different elements, different chemical properties, e.g. ^40_18Ar and ^40_20Ca
  • isotones: same neutron number N, different Z and A, e.g. ^11_5B and ^12_6C, both N=6
  • don't confuse: iso-**TOPES** share a spot, iso-**BARS** a weight, iso-**TONES** a neutron count

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